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The benefits of deliberately modulating air-to-fuel ratio over a three-way catalyst are disputed. In this work, engine test cell experiments were carried out to assess the performance of a warmed-up Pd/Rh three-way catalyst. The objectives were threefold: first, to determine the best mode of operation; second, to determine if air-to-fuel ratio modulation enhances robustness to transient air-to-fuel ratio disturbances; third, to determine if the conversion efficiency can be manipulated by controlling the shape of the air-to-fuel ratio oscillation. It was observed that the highest conversion efficiency is obtained using a steady air-to-fuel ratio just rich of stoichiometric; however, this mode of operation lacks robustness with respect to transient disturbances and UEGO sensor errors. Robustness can be improved using an oscillating air-to-fuel ratio, but with a sacrifice in peak conversion efficiency.

Models often use time rather than strokes (crank-angle) as the independent variable to describe engine dynamics despite the fact that the dynamics of an internal combustion engine are intrinsically linked to the combustion events. In this paper, two models are developed in parallel in which not only the independent variable is changed but the notion of mass flows as well: flows are in [g/s] for the time-based model and in [g/st] for the event-based model. Both models are of the same computational complexity and show the same accuracy in validation. The investigation of the model properties shows that variations in the flow-related parameters are reduced by a factor of two to five for the event-based model. However, those of the crankshaft dynamics are increased. It is concluded that the model should be chosen in context of the control system to be designed.

Experiments were performed to measure the number-weighted particle size distributions emitted from a gasoline direct injection (GDI) engine. Measurements were made on a late model vehicle equipped with a direct injection spark ignition engine. The vehicle was placed on a chassis dynamometer, which was used to load the engine to road load at five different vehicle speeds ranging from 15 - 100 km/hr. Dilution of the exhaust aerosol was carried out using a two-stage dilution system in which the first stage dilution occurs as a free jet. Particle size distributions were measured using a TSI 3934 scanning mobility particle sizer. Generally speaking, the presence of the additives did not have a strong, consistent influence on the particle emissions from this engine. The polyether amine demonstrated a reduction in particle number concentration as compared to unadditized base fuel.

A turbulent combustion model is described for SI engines with large variations in mixture strength. The model is for a single gas phase fluid at high Reynolds number and treats combustion in the laminar flamelet regime, which is characterized by high Damkholer and low Karlovitz numbers. An assumed probability density function (pdf) approach is used to extract expressions for mean quantities of interest, which are parameterized on the progress variable and mixture fraction variables. A double delta function pdf is used for the reaction progress variable and a beta function pdf is used for the mixture fraction. The reaction rate term in the progress variable equation is closed using an algebraic expression, which incorporates the effects of mixture strength, pressure and temperature on laminar flame speed. The model is implemented in two versions of a Computational Fluid Dynamics (CFD) code.

A fast response sensor for measuring carbon dioxide concentration has been developed for laboratory research and tested on a spark ignition engine. The sensor uses the well known infra-red absorption technique with a miniaturized detection system and short capillary sampling tubes, giving a time constant of approximately 5 milliseconds; this is sufficiently fast to observe changes in CO2 levels on a cycle-by-cycle basis under normal operating conditions. The sensor is easily located in the exhaust system and operates continuously. The sensor was tested on a standard production four cylinder spark-ignition engine to observe changes in CO2 concentration in exhaust gas under steady state and transient operating conditions. The processed sensor signal was compared to a standard air-to-fuel ratio (AFR) sensor in the exhaust stream and the results are presented here. The high frequency response CO2 measurements give new insights into both engine and catalyst transient operation.

Experiments were performed to measure the average and time-resolved particle number emissions and number-weighted particle size distributions from a gasoline direct injection (GDI) engine. Measurements were made on a late model vehicle equipped with a direct injection spark ignition engine. The vehicle was placed on a chassis dynamometer, which was used to load the engine to road load at five different vehicle speeds ranging from 13 - 90 km/hr. Particle number emissions were measured using a TSI 3020 condensation nucleus counter, and size distributions were measured using a TSI 3934 scanning mobility particle sizer. Average polydisperse number concentration was found to increase from 1.1 × 108 particles/cm3 at 13 km/hr to 2.8 × 108 particles/cm3 at 70 km/hr. Under a closed-loop, stoichiometric homogeneous charge operating mode at 90 km/hr, number emissions fell to 9.3 × 107 particles/cm3 (at all other operating conditions, the engine was in a lean stratified charge operating mode).

This paper presents two new methods to quantitatively evaluate the mechanical durability of multi-layered automotive paint systems. The first examines the resistance of the paint system to particle impacts and involves the impact of hard particles against the painted surface, under controlled conditions. The second test examines the resistance of the clearcoat layer in the paint system to surface abrasion, or mar. The test uses a steel sphere which is rotated against the paint surface in the presence of a slurry of fine abrasive particles. These two techniques have been successfully applied to a set of commercial automobile paints, and were found to discriminate well between them and give reproducible, quantitative data. The effects of the bake conditions on both the erosion and abrasion resistance of a full paint system and the abrasion resistance of a range of commercial clearcoats are examined in detail.

The gas velocity through an automotive catalyst has been determined by measuring the time of flight of a pulse of propane injected at the inlet plane of the catalyst. The arrival time at the exit plane was detected by a fast flame ionization detector. By synchronizing and delaying the injection of propane with respect to the engine crankshaft position, the fluctuations of the exhaust gas velocity during the engine cycle were investigated. A number of tests at different engine load and speed points were carried out. The results show a complex velocity/time characteristic, including flow reversals. The technique is shown to be a viable option for flow measurement in this harsh environment.

This paper presents the findings of theoretical and practical studies of an exhaust-gas reforming process, as applied to hydrocarbon fuels. It is shown that hydrogen-containing gaseous reformed fuels can be produced by the interaction of hot combustion products and an n-heptane feedstock in a small-scale catalytic reforming reactor. Predicted and observed reformed fuel chemical compositions were found to correlate well at the lower reactor space velocities tested, where chemical equilibrium conditions can be closely approached. Under these conditions, respective hydrogen and carbon monoxide yields of around 32 and 20 volume per cent were obtained. Under certain conditions, it was found that carbon solids were deposited on the reforming catalyst. Measures taken to avoid this problem included changes in the reforming oxidant to fuel ratio, and the addition of excess steam to the oxidant composition.

Afterburning of a rich exhaust/air mixture ahead of the catalyst has been shown in earlier papers to offer an effective means of achieving catalyst light-off in very short times. Protection of the catalyst from overheating is an important aspect of systems using EGI, and on board diagnostics will be required to check for proper function of EGI. In this paper, some options for these requirements are discussed, using a high temperature linear thermistor.

This paper describes a novel catalytic oxidation sensor which represents an attempt to realise a practical sensor for on vehicle detection of catalyst efficiency and misfire. Via experimental and modelling approaches, promising characteristics are established, which could mean that an application to the on-vehicle detection of catalyst efficiency and misfire is feasible.

Flamelet modelling of premixed turbulent combustion can be applied to spark-ignition engine combustion. To address and validate several modelling criteria, two measurement techniques are used in a burner flame to study the interaction between turbulent flowfields and combustion for subsequent application to engine combustion. Particle Image Velocimetry and Light Sheet Tomography are used together to measure conditional velocities simultaneously in reactant and product mixtures. Correlations of velocity and reaction scalar fluctuations indicate that counter-gradient turbulent diffusion must be accounted for when modelling this flowfield. Comparisons of spatial averaging of instantaneous and ensemble-averaged data are made and the application of similar techniques to engine combustion is discussed.

Using a novel, high frequency response FID unit, hydrocarbon measurements in the spark plug gap of a firing gasoline engine have been made. These measurements have been correlated with the pressure development, and a significant correlation was found. The method described can be used on any engine fitted with a modified sparking plug.

The relationship between H2S emissions from three-way catalysts and the storage of sulphur on the catalyst surface has been investigated. Thermodynamic data predict that sulphur storage primarily will occur on Al2O3 and CeO2 under lean and stoichiometric conditions, at up to 500°C. Rich transients could then induce the decomposition of the Ce-S-O and Al-S-O compounds, releasing sulphur into the gas phase. Experimental studies have supported this model. A mechanism has been proposed for the subsequent formation of H2S. The mechanism by which catalyst poisons attenuate H2S emissions from engine-aged catalysts also has been studied. The effect has been shown to be related to decreased storage of sulphur, caused by stable catalyst-poison species at the catalyst surface.